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Speciation diagram
of CO2/HCO3/CO32−
as a function of pH

Created by Gábor Turu



Some plant species seem to need a slightly acidic pH (pH < 6) to growth well under some conditions (see picture below). Suppose your aquarium water has a KH of 1 (similar to Tom Barr, Gregg Zydeck, or Joe Harvey to name a few). Find out how much CO2 would you need to add to your aquarium to bring the pH down below 6. Hint: Enormous!
PS: Tom Barr's pH is 5.6 [when CO2 injection is on], and Gregg Zydeck's is said to be as low as 5.4 (see 2hraquarist.com). So now you can probably guess why it is "necessary" to add such a huge amount of CO2 to the aquarium if you want to meet the pH needs of some acid-loving plants. Yet the best way to achieve the desired pH is not to add excessive amounts of CO2 to the water, but to remove bicarbonate from it. With 0.1°dKH you only need to add 10 ppm CO2 to the water to achieve the same pH as Tom Barr with 1°dKH and 88 ppm CO2! And yet your plants will grow just as well in this aquarium as in his.
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